CIE A Level Chemistry复习笔记7.1.5 Shape of Aromatic Molecules

• Aromatic molecules consist of one or more rings with conjugated π systems
• Conjugated π systems arise from alternating double and single bonds in which the electrons are delocalised
• Aromatic compounds are called ‘aromatic’ as they often have pleasant odours

 Examples of aromatic compounds including benzene table

Shape of benzene & aromatic compounds

• Benzene and other aromatic compounds contain sp² hybridised carbons as two of their p orbitals have mixed with an s orbital
• This means that each carbon atom in benzene and other aromatic compounds has one p orbital

The carbon atoms in aromatic compounds are sp² hybridized as two of their p orbitals mix with an s orbital

• Each carbon atom in the ring forms three σ bonds using the sp² orbitals
• The remaining p orbital overlaps laterally with p orbitals of neighbouring carbon atoms to form a π bond
• This extensive sideways overlap of p orbitals results in the electrons being delocalised and able to freely spread over the entire ring
• Benzene and other aromatic compounds are regular and planar compounds with bond angles of 120^o
• The delocalisation of electrons means that all of the carbon-carbon bonds in these compounds are identical and have both single and double bond character
• The bonds all being the same length is evidence for the delocalised ring structure of benzene

Like other aromatic compounds, benzene has a planar structure due to the sp² hybridisation of carbon atoms and the conjugated π system in the ring